Preheat the oven to 350°F (175°C). Grease and line an 8 × 8-inch (20cm) square baking pan with an overhang of baking paper.
Combine the warm milk and white vinegar. Let sit for 5 minutes. Add sugar, vanilla extract and oil, then whisk until combined.
In a separate bowl, whisk together the flour, cocoa powder, baking soda, baking powder, cinnamon powder and salt. Add the dry ingredients to the wet ingredients and mix just until smooth.
Pour the batter into the prepared pan and spread evenly. Bake for 25-30 minutes, or until a toothpick inserted into the center comes out clean or with a few moist crumbs.